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Journal Articles Angewandte Chemie International Edition Year : 2014

Iron cyclopentadienone complexes: discovery, properties, and catalytic reactivity

Adrien Quintard
Jean Rodriguez
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Abstract

Iron cyclopentadienone complexes have recently received particular attention in organic chemistry. This is due to their easy synthesis from simple and cheap materials, air-water stability, and most importantly for their unique catalytic features arising from the presence of a noninnocent ligand, triggering powerful redox properties. Herein we discuss the properties of such complexes from synthetic and mechanistic points of view, and their applications in original redox-neutral transformations in both racemic and enantioselective series.

Dates and versions

hal-01066305 , version 1 (19-09-2014)

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Adrien Quintard, Jean Rodriguez. Iron cyclopentadienone complexes: discovery, properties, and catalytic reactivity. Angewandte Chemie International Edition, 2014, 53, pp.4044-4055. ⟨10.1002/anie.201310788⟩. ⟨hal-01066305⟩
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