An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols - Aix-Marseille Université Access content directly
Journal Articles Angewandte Chemie International Edition Year : 2013

An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols

Abstract

An enantioselective transformation of allylic alcohols into β-chiral saturated alcohols has been developed by combining two distinct metal- and organocatalyzed catalytic cycles. This waste-free triple cascade process merges an iron-catalyzed borrowing-hydrogen step with an aminocatalyzed nucleophilic addition

Dates and versions

hal-01133519 , version 1 (19-03-2015)

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Adrien Quintard, Thierry Constantieux, Jean Rodriguez. An Iron/Amine-Catalyzed Cascade Process for the Enantioselective Functionalization of Allylic Alcohols. Angewandte Chemie International Edition, 2013, 52, pp.12883-12887. ⟨10.1002/anie.201307295⟩. ⟨hal-01133519⟩
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