%0 Journal Article %T Enamine Activation of beta-Ketocarbonyls: New Opportunities in Enantioselective Organocatalysis %+ Institut des Sciences Moléculaires de Marseille (ISM2) %A Rodriguez, Jean %A Coquerel, Yoann %< avec comité de lecture %@ 1867-3899 %J ChemCatChem %I Wiley %V 7 %P 1263 %8 2015-04-07 %D 2015 %R 10.1002/cctc.201500159 %K 1 %K 3-dicarbonyls %K enantioselective catalysis %K enantioselectivity %K organocatalysis %K synthetic methods %Z Chemical Sciences/Organic chemistryJournal articles %X Enamine activation of alpha-branched beta-ketocarbonyl compounds is actually possible, very efficient, and highly enantioselective with a bifunctional primary amine/tertiary ammonium triflate salt catalyst. This covalent HOMO activation mode competes with existing strategies for the enantioselective activation of beta-ketocarbonyls and their analogues. %G English %L hal-01224298 %U https://hal.science/hal-01224298 %~ CNRS %~ UNIV-AMU %~ EC-MARSEILLE %~ ISM2 %~ INC-CNRS %~ ANR %~ TEST2-HALCNRS