Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N-(aza[6]helicenyl)-NHC ligand - Aix-Marseille Université Access content directly
Journal Articles Chemistry - A European Journal Year : 2023

Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N-(aza[6]helicenyl)-NHC ligand

Abstract

The photophysical and chiroptical properties of a novel, chiral helicene-NHC-Re(I) complex bearing an N-(aza[6]helicenyl)-benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative analysis of this new system with other helicene-Re(I) complexes reported to date illustrates the impact of structural modifications on the emissive and absorptive properties.
Fichier principal
Vignette du fichier
Chemistry A European J - 2023 - Gauthier - Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium I .pdf (2.58 Mo) Télécharger le fichier
Origin : Publication funded by an institution
Licence : CC BY - Attribution

Dates and versions

hal-03971868 , version 1 (03-04-2023)

Licence

Attribution

Identifiers

Cite

Etienne S. Gauthier, Laura Abella, Elsa Caytan, Thierry Roisnel, Nicolas Vanthuyne, et al.. Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N-(aza[6]helicenyl)-NHC ligand. Chemistry - A European Journal, 2023, ⟨10.1002/chem.202203477⟩. ⟨hal-03971868⟩
42 View
2 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More