Modulation of chiroptical and photophysical properties in helicenic rhenium(I) systems: the use of an N-(aza[6]helicenyl)-NHC ligand
Abstract
The photophysical and chiroptical properties of a novel, chiral helicene-NHC-Re(I) complex bearing an N-(aza[6]helicenyl)-benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative analysis of this new system with other helicene-Re(I) complexes reported to date illustrates the impact of structural modifications on the emissive and absorptive properties.
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Chemistry A European J - 2023 - Gauthier - Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium I .pdf (2.58 Mo)
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Origin : Publication funded by an institution
Licence : CC BY - Attribution
Licence : CC BY - Attribution