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Journal Articles Tetrahedron Letters Year : 2014

An expeditious method for the selective cyclotrimerization of isocyanates initiated by TDAE

Abstract

We developed a rapid and green synthesis of various isocyanurates by cyclotrimerization of isocyanates using TDAE (tetrakis(dimethylamino)ethylene). TDAE displays excellent performance in catalytic quantities , affording the corresponding trimer of isocyanates very rapidly, under air and at room temperature in good to excellent yields.
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Dates and versions

hal-01425614 , version 1 (12-01-2017)

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Alain G Giuglio-Tonolo, Cédric Spitz, Thierry Terme, Patrice Vanelle. An expeditious method for the selective cyclotrimerization of isocyanates initiated by TDAE. Tetrahedron Letters, 2014, 55 (16), pp.2700 - 2702. ⟨10.1016/j.tetlet.2014.03.045⟩. ⟨hal-01425614⟩
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