One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality - Aix-Marseille Université Access content directly
Journal Articles Chemical Communications Year : 2012

One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality

Abstract

The tandem Crabbe homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring alpha-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
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hal-01460405 , version 1 (07-02-2017)

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Shovan Mondal, Malek Nechab, Nicolas Vanthuyne, Michèle P. Bertrand. One-pot Crabbe homologation-radical cascade cyclisation with memory of chirality. Chemical Communications, 2012, 48 (19), pp.2549--2551. ⟨10.1039/c2cc17830c⟩. ⟨hal-01460405⟩
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