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Journal Articles Journal of Polymer Science Part A: Polymer Chemistry Year : 2012

Nitroxide-mediated controlled radical polymerizations of styrene derivatives

Patrick J. M. Stals
  • Function : Author
Didier Gigmes
Tim F. E. Paffen
  • Function : Author
Anja R. A. Palmans
  • Function : Author

Abstract

Several (protected) amine and alcohol functionalized styrene monomers were synthesized via readily accessible synthetic routes. The controlled radical copolymerization of these functionalized styrene monomers with styrene was performed using two alkoxyamines, namely N-(2-methylpropyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-O-(2-carbox ylprop-2-yl) hydroxylamine (MAMA-SG1) and N-tert-butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine. The copolymers obtained showed low polydispersities, controlled molecular weights, and a random topology. The thermal properties of the polymers were determined with differential scanning calorimetry. All polymers were amorphous and showed glass transition temperatures between

Dates and versions

hal-01460425 , version 1 (07-02-2017)

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Patrick J. M. Stals, Trang N. T. Phan, Didier Gigmes, Tim F. E. Paffen, E. W. Meijer, et al.. Nitroxide-mediated controlled radical polymerizations of styrene derivatives. Journal of Polymer Science Part A: Polymer Chemistry, 2012, 50 (4), pp.780--791. ⟨10.1002/pola.25833⟩. ⟨hal-01460425⟩
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