Novel polymer synthesis methodologies using combinations of thermally- and photochemically-induced nitroxide mediated polymerization - Aix-Marseille Université Access content directly
Journal Articles Polymer Chemistry Year : 2015

Novel polymer synthesis methodologies using combinations of thermally- and photochemically-induced nitroxide mediated polymerization

Jason Morris
  • Function : Author
Kathryn E. Fairfull-Smith
  • Function : Author
Steven E. Bottle
  • Function : Author
Yohann Guillaneuf
Didier Gigmes

Abstract

The combination of thermally-and photochemically-induced polymerization using light sensitive alkoxy-amines was investigated. The thermally driven polymerizations were performed via the cleavage of the alkoxyamine functionality, whereas the photochemically-induced polymerizations were carried out either by nitroxide mediated photo-polymerization (NMP2) or by a classical type II mechanism, depending on the structure of the light-sensitive alkoxyamine employed. Once the potential of the various structures as initiators of thermally-and photo-induced polymerizations was established, their use in combination for block copolymer syntheses was investigated. With each alkoxyamine investigated, block copolymers were successfully obtained and the system was applied to the post-modification of polymer coatings for application in patterning and photografting.

Dates and versions

hal-01460638 , version 1 (07-02-2017)

Identifiers

Cite

Jason Morris, Sofia Telitel, Kathryn E. Fairfull-Smith, Steven E. Bottle, Jacques Lalevee, et al.. Novel polymer synthesis methodologies using combinations of thermally- and photochemically-induced nitroxide mediated polymerization. Polymer Chemistry, 2015, 6 (5), pp.754--763. ⟨10.1039/c4py01270d⟩. ⟨hal-01460638⟩
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