Synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides via a double Mitsunobu-type reaction - Aix-Marseille Université Access content directly
Journal Articles Tetrahedron Letters Year : 2002

Synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides via a double Mitsunobu-type reaction

Abstract

This letter describes the synthesis of (±) cis -substituted cyclohexenyl and cyclohexanyl nucleosides. The synthesis of cis isomers was successfully achieved by the use of two consecutive Mitsunobu reactions involving an inversion of configuration and a sugar–base condensation.

Dates and versions

hal-02061647 , version 1 (08-03-2019)

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Karine Barral, Philippe Halfon, Gérard Pèpe, Michel Camplo. Synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides via a double Mitsunobu-type reaction. Tetrahedron Letters, 2002, 43 (1), pp.81-84. ⟨10.1016/S0040-4039(01)02107-4⟩. ⟨hal-02061647⟩
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