Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP) - Aix-Marseille Université Access content directly
Journal Articles Australian Journal of Chemistry Year : 2018

Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)


Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)(2) (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90 degrees C.
No file

Dates and versions

hal-02091929 , version 1 (06-04-2019)



Gérard Audran, Elena Bagryanskaya, Mariya Edeleva, Sylvain R.A. Marque, Dmitriy Parkhomenko, et al.. Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). Australian Journal of Chemistry, 2018, 71 (5), pp.334--340. ⟨10.1071/CH17570⟩. ⟨hal-02091929⟩
22 View
0 Download



Gmail Facebook X LinkedIn More